{"id":8707,"date":"2021-06-02T10:10:01","date_gmt":"2021-06-02T06:10:01","guid":{"rendered":"http:\/\/round-the-world.org\/?p=8707"},"modified":"2021-06-02T10:11:20","modified_gmt":"2021-06-02T06:11:20","slug":"%d0%bc%d0%b5%d1%85%d0%b0%d0%bd%d0%b8%d0%b7%d0%bc-%d0%b0%d0%b1%d0%b8%d0%be%d0%b3%d0%b5%d0%bd%d0%bd%d0%be%d0%b3%d0%be-%d1%81%d0%b8%d0%bd%d1%82%d0%b5%d0%b7%d0%b0-%d0%bd%d1%83%d0%ba%d0%bb%d0%b5%d0%b8","status":"publish","type":"post","link":"http:\/\/round-the-world.org\/?p=8707","title":{"rendered":"\u041c\u0435\u0445\u0430\u043d\u0438\u0437\u043c \u0430\u0431\u0438\u043e\u0433\u0435\u043d\u043d\u043e\u0433\u043e \u0441\u0438\u043d\u0442\u0435\u0437\u0430 \u043d\u0443\u043a\u043b\u0435\u0438\u043d\u043e\u0432\u044b\u0445 \u043a\u0438\u0441\u043b\u043e\u0442 \u043d\u0430\u0439\u0434\u0435\u043d"},"content":{"rendered":"\n<p>\u0412 \u044d\u043a\u0441\u043f\u0435\u0440\u0438\u043c\u0435\u043d\u0442\u0430\u0445 \u0430\u043d\u0430\u043b\u043e\u0433\u0438\u0447\u043d\u044b\u0445 \u044d\u043a\u0441\u043f\u0435\u0440\u0438\u043c\u0435\u043d\u0442\u0443 \u041c\u0438\u043b\u043b\u0435\u0440\u0430-\u042e\u0440\u0438, \u0438\u0437 \u0441\u0438\u043d\u0438\u043b\u044c\u043d\u043e\u0439 \u043a\u0438\u0441\u043b\u043e\u0442\u044b \u0438 \u0432\u043e\u0434\u044b \u043f\u043e\u043b\u0443\u0447\u0430\u044e\u0442\u0441\u044f \u043f\u0440\u0435\u0434\u0448\u0435\u0441\u0442\u0432\u0435\u043d\u043d\u0438\u043a\u0438 \u0431\u0435\u043b\u043a\u043e\u0432 \u0438 \u0420\u041d\u041a \u043f\u043e\u043a\u0430\u0437\u0430\u043d\u043e \u0432 \u0441\u0442\u0430\u0442\u044c\u0435 \u0432\u00a0<a rel=\"noreferrer noopener\" href=\"http:\/\/pubs.acs.org\/%E2%80%8Bdoi\/%E2%80%8Babs\/%E2%80%8B10.%E2%80%8B1021\/%E2%80%8Bacscentsci.%E2%80%8B9b00520\" target=\"_blank\">ACS Central Science.<\/a> \u041d\u043e, \u0432 \u0430\u0431\u0438\u043e\u043b\u043e\u0433\u0438\u0447\u0435\u0441\u043a\u0438\u0445 \u0443\u0441\u043b\u043e\u0432\u0438\u044f\u0445, \u043a\u0440\u0438\u0441\u0442\u0430\u043b\u043b\u044b \u0430\u043d\u0430\u043b\u043e\u0433\u0438\u0447\u043d\u044b\u0435 \u0414\u041d\u041a  \u0438 \u0420\u041d\u041a \u043f\u043e\u043b\u0443\u0447\u0430\u044e\u0442\u0441\u044f \u043e\u0447\u0435\u043d\u044c \u043a\u0440\u043e\u0442\u043a\u0438\u043c\u0438. \u0425\u0438\u043c\u0438\u043a\u0438 \u0438\u0437 \u0438\u043d\u0441\u0442\u0438\u0442\u0443\u0442\u0430\u00a0Scripps Research \u0432 \u0421\u0430\u043d-\u0414\u0438\u0435\u0433\u043e, \u041a\u0430\u043b\u0438\u0444\u043e\u0440\u043d\u0438\u044f \u0441\u0434\u0435\u043b\u0430\u043b\u0438 <a href=\"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.202015910\">\u043e\u0442\u043a\u0440\u044b\u0442\u0438\u0435<\/a> \u043f\u0440\u043e\u0441\u0442\u043e\u0433\u043e \u0445\u0438\u043c\u0438\u0447\u0435\u0441\u043a\u043e\u0433\u043e \u0432\u0435\u0449\u0435\u0441\u0442\u0432\u0430 \u0441\u043e\u0431\u0438\u0440\u0430\u044e\u0449\u0435\u0433\u043e \u043d\u0435\u0431\u043e\u043b\u044c\u0448\u0438\u0435 \u043a\u0440\u0438\u0441\u0442\u0430\u043b\u043b\u044b \u0430\u0431\u0438\u043e\u0433\u0435\u043d\u043d\u044b\u0445 \u043d\u0443\u043a\u043b\u0435\u0438\u043d\u043e\u0432\u044b\u0445 \u043a\u0438\u0441\u043b\u043e\u0442 \u0432 \u0434\u043b\u0438\u043d\u043d\u044b\u0435 \u0446\u0435\u043f\u043e\u0447\u043a\u0438. \u041e\u0442\u043a\u0440\u044b\u0442\u0438\u0435 \u043e\u043f\u0443\u0431\u043b\u0438\u043a\u043e\u0432\u0430\u043d\u043e \u0432\u00a0Angewandte Chemie.<\/p>\n\n\n\n<figure class=\"wp-block-image\"><img decoding=\"async\" src=\"https:\/\/avatars.mds.yandex.net\/get-zen_doc\/4453741\/pub_60b64baa86027a36235ec344_60b64c9fcee36237b8fa0b70\/scale_1200\" alt=\"\"\/><\/figure>\n\n\n\n<p>\u0423\u0447\u0435\u043d\u044b\u0435 \u0432\u044b\u044f\u0441\u043d\u0438\u043b\u0438, \u0447\u0442\u043e \u0441\u043e\u0437\u0434\u0430\u0442\u044c \u0434\u043b\u0438\u043d\u043d\u044b\u0435 \u0446\u0435\u043f\u043e\u0447\u043a\u0438 \u043d\u0443\u043a\u043b\u0435\u0438\u043d\u043e\u0432\u044b\u0445 \u043a\u0438\u0441\u043b\u043e\u0442 \u043c\u043e\u0436\u0435\u0442 \u0434\u0438\u0430\u043c\u0438\u0434\u043e\u0444\u043e\u0441\u0444\u0430\u0442 (DAP). \u042d\u0442\u043e \u0432\u0435\u0449\u0435\u0441\u0442\u0432\u043e \u043c\u043e\u0436\u0435\u0442 \u0432\u043e\u0437\u043d\u0438\u043a\u0430\u0442\u044c \u043d\u0430 \u043b\u044e\u0431\u043e\u0439 \u043f\u043b\u0430\u043d\u0435\u0442\u0435 \u0434\u043e \u0432\u043e\u0437\u043d\u0438\u043a\u043d\u043e\u0432\u0435\u043d\u0438\u044f \u0436\u0438\u0437\u043d\u0438.<\/p>\n\n\n\n<p>Diamidophosphate (DAP) \u0432\u043f\u0435\u0440\u0432\u044b\u0435 \u0431\u044b\u043b \u0438\u0441\u043f\u043e\u043b\u044c\u0437\u043e\u0432\u0430\u043d \u0434\u043b\u044f \u0444\u043e\u0441\u0444\u043e\u0440\u0438\u043b\u0438\u0440\u043e\u0432\u0430\u043d\u0438\u044f \u0441\u0430\u0445\u0430\u0440\u043e\u0432 \u0432 \u0432\u043e\u0434\u043d\u043e\u0439 \u0441\u0440\u0435\u0434\u0435. \u0414\u0438\u0430\u043c\u0438\u0434\u043e\u0444\u043e\u0441\u0444\u0430\u0442 \u043c\u043e\u0436\u0435\u0442 \u043e\u0431\u0440\u0430\u0437\u043e\u0432\u044b\u0432\u0430\u0442\u044c \u0441\u043e\u043b\u0438, \u0442\u0430\u043a\u0438\u0435 \u043a\u0430\u043a \u0434\u0438\u0430\u043c\u0438\u0434\u043e\u0444\u043e\u0441\u0444\u0430\u0442 \u043d\u0430\u0442\u0440\u0438\u044f \u0438\u043b\u0438 \u043a\u0438\u0441\u043b\u0430\u044f \u0444\u043e\u0441\u0444\u043e\u0440\u043e\u0434\u0438\u0430\u043c\u0438\u0434\u043d\u0430\u044f \u043a\u0438\u0441\u043b\u043e\u0442\u0430. \u0424\u043e\u0441\u0444\u043e\u0440\u043e\u0434\u0438\u0430\u043c\u0438\u0434\u043d\u0430\u044f \u043a\u0438\u0441\u043b\u043e\u0442\u0430 \u043c\u043e\u0436\u0435\u0442 \u043a\u0440\u0438\u0441\u0442\u0430\u043b\u043b\u0438\u0437\u043e\u0432\u0430\u0442\u044c\u0441\u044f \u0432 \u0432\u0438\u0434\u0435 \u0442\u0440\u0438\u0433\u0438\u0434\u0440\u0430\u0442\u0430. <\/p>\n\n\n\n<p>\u0410\u0432\u0442\u043e\u0440\u044b \u043e\u0442\u043a\u0440\u044b\u0442\u0438\u044f \u0443\u0447\u0451\u043d\u044b\u0435\u00a0\u0418\u0441\u0441\u043b\u0435\u0434\u043e\u0432\u0430\u0442\u0435\u043b\u044c\u0441\u043a\u043e\u0433\u043e \u0438\u043d\u0441\u0442\u0438\u0442\u0443\u0442\u0430 \u0421\u043a\u0440\u0438\u043f\u043f\u0441\u0430 (Scripps Research) \u044d\u0442\u043e \u043b\u044e\u0434\u0438 \u0437\u0430\u0448\u043e\u0440\u0435\u043d\u043d\u044b\u0435 \u0438\u0434\u0435\u0435\u0439, \u0447\u0442\u043e \u0438\u043c\u0435\u043d\u043d\u043e \u043d\u0430 \u0417\u0435\u043c\u043b\u0435 \u0436\u0438\u0437\u043d\u044c \u0432\u043e\u0437\u043d\u0438\u043a\u043b\u0430 \u0430\u0431\u0438\u043e\u0433\u0435\u043d\u043d\u043e, \u043d\u043e \u0440\u0435\u0430\u043b\u044c\u043d\u0435\u0435 \u043f\u0440\u0435\u0434\u0441\u0442\u0430\u0432\u043b\u0435\u043d\u0438\u0435, \u0447\u0442\u043e \u0436\u0438\u0437\u043d\u044c \u0440\u0430\u0441\u043f\u0440\u043e\u0441\u0442\u0440\u0430\u043d\u044f\u0435\u0442\u0441\u044f \u0432 \u043f\u0440\u043e\u0446\u0435\u0441\u0441\u0435 \u043f\u0430\u043d\u0441\u043f\u0435\u0440\u043c\u0438\u0438, \u0445\u043e\u0442\u044f \u043f\u0440\u0435\u0434\u043f\u043e\u0441\u044b\u043b\u043a\u0438 \u0434\u043b\u044f \u0435\u0451 \u0430\u0432\u0442\u043e\u043d\u043e\u043c\u043d\u043e\u0433\u043e \u0432\u043e\u0437\u043d\u0438\u043a\u043d\u043e\u0432\u0435\u043d\u0438\u044f \u0438\u043c\u0435\u044e\u0442\u0441\u044f \u0438 \u0433\u0434\u0435-\u0442\u043e \u0438 \u043a\u043e\u0433\u0434\u0430-\u0442\u043e \u0440\u0435\u0430\u043b\u0438\u0437\u0443\u044e\u0442\u0441\u044f.<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u0412 \u044d\u043a\u0441\u043f\u0435\u0440\u0438\u043c\u0435\u043d\u0442\u0430\u0445 \u0430\u043d\u0430\u043b\u043e\u0433\u0438\u0447\u043d\u044b\u0445 \u044d\u043a\u0441\u043f\u0435\u0440\u0438\u043c\u0435\u043d\u0442\u0443 \u041c\u0438\u043b\u043b\u0435\u0440\u0430-\u042e\u0440\u0438, \u0438\u0437 \u0441\u0438\u043d\u0438\u043b\u044c\u043d\u043e\u0439 \u043a\u0438\u0441\u043b\u043e\u0442\u044b \u0438 \u0432\u043e\u0434\u044b \u043f\u043e\u043b\u0443\u0447\u0430\u044e\u0442\u0441\u044f \u043f\u0440\u0435\u0434\u0448\u0435\u0441\u0442\u0432\u0435\u043d\u043d\u0438\u043a\u0438 \u0431\u0435\u043b\u043a\u043e\u0432 \u0438 \u0420\u041d\u041a \u043f\u043e\u043a\u0430\u0437\u0430\u043d\u043e \u0432 \u0441\u0442\u0430\u0442\u044c\u0435 \u0432\u00a0ACS Central&#8230;<br \/><a class=\"read-more-button\" href=\"http:\/\/round-the-world.org\/?p=8707\">\u0414\u0410\u041b\u0415\u0415<\/a><\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[9],"tags":[],"class_list":["post-8707","post","type-post","status-publish","format-standard","hentry","category-9"],"_links":{"self":[{"href":"http:\/\/round-the-world.org\/index.php?rest_route=\/wp\/v2\/posts\/8707","targetHints":{"allow":["GET"]}}],"collection":[{"href":"http:\/\/round-the-world.org\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/round-the-world.org\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/round-the-world.org\/index.php?rest_route=\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"http:\/\/round-the-world.org\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=8707"}],"version-history":[{"count":1,"href":"http:\/\/round-the-world.org\/index.php?rest_route=\/wp\/v2\/posts\/8707\/revisions"}],"predecessor-version":[{"id":8708,"href":"http:\/\/round-the-world.org\/index.php?rest_route=\/wp\/v2\/posts\/8707\/revisions\/8708"}],"wp:attachment":[{"href":"http:\/\/round-the-world.org\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=8707"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/round-the-world.org\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=8707"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/round-the-world.org\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=8707"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}